INDUSTRIAS BASICAS DE CALDAS SUCCESSFUL CASE

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Héctor Cipriano González Vargas Rogelio Grisales Rincón.

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Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.

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o gug g v/i. Introduction. 01.

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00 00 00. Sulphur burning , contact method with double absorption in a (3+1) arrangement.

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Is there a PROBLEM ?. 02.

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We need to remove minimum the 90% of sulphates in the wastewater effluent or prevent their generation in the origin..

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EVALUATION OF ALTERNATIVES. 03.

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The final decision was to carried out a project to evaluate technical and economical feasibility to r eturn t he sulphonation exhaust gas to the sulphuric acid plant and recover the Sulphur dioxide.

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RETORNO SO 2. PLANT TESTS. 04.

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Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.

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Diagrama Descripci n generada autom ticamente. Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.

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A risk analysis was made using Hazop methodology.

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Flowchart to the first six (6) test runs. to Stack Scrubber sog 02 Mist Electrostatic precipitator Caustic soda HV02 HVOI 02 50K1 to Acid H o Hot heat exchanger Cold heat exchanger um tank Intermediate absorption tower from Sulphur burner to Economizer Catalytic converter Sulphonation plant Sulphuric acid plant.

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PLANT TEST. Goals. Evaluate feasibility Establish operating conditions Validate risks and security.

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PLANT TEST. Results. Maximum capacity achived : 90 MTPD Discharge of the main blower, pressure drops, SO2 emissions in the stack, acid turbidity and iron content increased within acceptable limits according to quality specifications.

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Results. The presence of acid mists in the intermediate absorption tower was not evidenced Wood test negative.

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PLANT TEST. Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.

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Goals. Determine the maximum gas flow that was possible to recover with maximum production capacity (125 MTPD ).

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Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.

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PLANT TEST. Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.

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NEW BED CATALYST. . From gas filter. … To Converter.

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NEW BLOWER. .

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RESULTS AND CONCLUSIONS. 05.

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Return of exhaust gas from sulfonation line to the sulfuric acid plant to recover sulphur dioxide Sulphur + Sulphuric Acid.