HazCom Training: GHS Safety Data Sheets (SDS)

to Read a Safety Data Sheet DATA SHEETS ITER SAFETY DATA SHEETR.

solvent X Warning Methylene ULINE H-22 9M-R FLAMMABLE LIQUID STORAGE CABINET A DANGEÆ Fuel storage area. No smoking. No open flame..

What You’ll Learn. After completing this course, you will be able to: Describe how the Hazard Communication Standard keeps you safe from the dangers of hazardous chemicals Explain what information can be found in each section of a chemical’s Safety Data Sheet Describe how Safety Data Sheets can help you work safely with chemicals.

Hazardous Chemicals.

suusu u uumuu upaqopo« Irs. HazCom Standard. Requires your employer inform you of: Chemicals being used in your workplace The associated hazards How to protect yourself Exists to help: Prevent injuries and illnesses Save lives Improve trade conditions.

i:.v41. HazCom Standard. OSHA adopted the GHS hazard definitions, the container label elements, and the format and content of safety data sheets (SDSs)..

Safety Data Sheets.

Sheet DATA SHEET INFORMATION HERE 000000000. Safety Data Sheets (SDSs).

'////4////i/j;•. 1. Product and Company Identification Product Name: Solvent X Synonvms: Machine solvent, industrial solvent, equipment flushing solvent CAS Not applicable to mixtures Molecular Weight: Not applicable to mixtures Emergency Contact: +1-123-555-1212 Product Use: Various industrial uses Restrictions: Not to be used as a skin cleaner Chemical Formula: Not applicable to mixtures Product Codes: UR-IOI Manufacturer: U. R. Chemical Little Hill Dr. Little Hill, KS 01234 Telephone: +1-123-555-0101 Fax: +1-123-555-0102.

Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Phosphoric Acid solution. 40% Redi-metal Prep use to clean. degrease, and etch metal prior to coating. ABC Chemical '23 Safety Lane Danas. Tx 75038 Phone '-goo-555-'2'2 FAX '-BOO-555.'4'4 Emergency Phone Number: 866-987-6543 2. HAZARD(S) IDENTIFICATION Hazard Classification : Acute toxicity, Oral (Category 4) Acute toxicity Inhalation (Category 2) Acute toxicity. Derma/ (Category 5) Skin corrosion (Category 1B) Serious eye damage (Category t) SECTION Signa' word: Hazard statement(s): H302 H3'3 H3'4 autiona Danger Harmful if swallowed. May be harmful in contact with skin. Causes severe skin b and eye damage. Fata/ if inhaled. not br s/ mist/ vapours/ spray, five clothing/ eye protection/ face protection. with water for several minutes. Remove contact lenses. Continue rinsing, ON CENTER or doctor/ physician. e Phosphoric Acid.

3. Composition/lnformation on Ingredients Ingredient Methylene Chloride Ethyl Alcohol Acetic Acid Paraffinic Petroleum Distillates CAS No 75-09-2 64-17-5 64-19_7 64742-65-0 Percent 40% 15% Hazardous Yes Yes Yes Yes.

4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. If breathing stops, administer artificial respiration. Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention immediately. Skin Contact: Remove contaminated clothing and shoes. Wash exposed area with soap and water for at least 15 minutes. Get medical advice if ilTitation develops. Wash contaminated clothing before reuse. Eye Contact: Flush thoroughly with running water for at least 15 minutes, occasionally lifting the eyelids. Obtain medical attention..

5. Fire Fighting Measures Fire: Fire is possible if concentrated vapors are exposed to elevated temperatures. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode..

6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up spill for recovery or disposal and place in a closed container. Keep spilled material away from sewage/drainage systems and waterways..

7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Observe all warnings and precautions listed for the product..

ALCOHOL. Section 8: Exposure Controls / Personal Protection.

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ooe•ooco. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Strong oxidizers and reactive metals. Conditions to Avoids: Incompatibles and hot surfaces which can cause thermal decomposition..

11. Toxicological Information Methylene chloride: oral rat LD50: 16000mg/kg•, inhalation rat LC50: 52gm/m3; investigated as a tumorigen, mutagen, reproductive effector. Ethyl alcohol: oral rat LD50= 7060mg/kg; inhalation rat LC50= 20,000ppm/10H; investigated as a tumorigen, mutagen, reproductive effector. Acetic acid: No LD50/LC50 information found relating to normal routes of occupational exposure. Paraffinic petroleum distillates: Not known..

12. Ecological Information Environmental Fate: When released into the soil, this material may biodegrade to a moderate extent. When released into the soil, this material is expected to leach into groundwater. When released into water, this material may biodegrade to a moderate extent. When released into the air, this material may be moderately degraded by reaction with photo- chemically produced hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30 days. Ecotoxicological Data: 96 hr. NOEL (minnow) 1 10 mg/L 24 hr EC50 (Daphnia Magna) 460 mg/L.

13. Disposal Considerations Recover or recycle if possible. It is the responsibility of the waste generator to determine the proper waste classification and disposal methods in compliance with ap- plicable federal, state, and local regulations. Do not dispose of in the environment, in drains or water courses. Drain container thoroughly. Send to recycler/reclaimer..

14. Transport Information Transport in accordance with all federal, state, and local regulations. UN number 2929 UN proper shipping name Toxic liquid, flammable, n.o.s. Hazards class 6. l; Packing Group III.

MSDS Number: Revision Date: Supersedes Date: EOCOOA 03 SEP 2010 01 JUL 2010 Plastics' REGULATORY INFORMATION U.N. GHS Classification & Labeling Information: Classification: Signal Word: H Statements: P Statements: F A 704 Inform n Health Rating Flammable Liquid 2 Eye irritant 2 Skin Irritant 2 Acute Toxicity 4 Specific Target Organ Toxicity (STOT) — Single Exposure 3 Carcinogen 1B DANGER H225: Highly flammable liquid and vapor. H302: Harmful if swallowenl. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. 1-4336: May cause dizziness or drowsiness. H350: May cause cancer. P210: away from heatjsparks/open flames/hot surfaces — No smoking• P240• Ground/bond container and receiving equipment. P307+313: If exposed. get medical attention. P281 use personal protective equipment as required. P264• Wash thoroughly after handling. P243. Take precautions against static discharge. P273. Avoid release into the environment. 3.

Sheet SHEET INFORMATION HERE -ooeo•oooø. 16. Other Information NFPA Ratings: Health: 3 Flammability: 1 Reactivity: 0 HMIS Ratings: Health: 3 Flammability: 1 Physical Hazard: O This SDS was prepared by U. R. Chemical. Revision Information: Revised 05/27/12.

DANGER. Intro to Safety Data Sheets.

How to Use SDSs. An SDS identifies information to keep you, your coworkers, and the environment safe..

*Risk Management Center Solvent X (contains Methylene Chloride).

'0000'. Summary. This training was designed to help you understand more about the Hazard Communication Standard and how the Safety Data Sheet can help you stay safe when working with chemicals..